Radiometric Dating

Earth Science

Radiometric dating measures the decay of radioactive isotopes in rocks or organic remains to calculate an absolute age in years.

Visualization

Definition

Radiometric dating is a way to find out how many years old a rock or fossil is: some atoms inside rocks slowly change into other atoms at a steady rate, so scientists count how many have changed to work out the age. The method relies on the constant decay rate of a radioactive parent isotope into a stable daughter isotope; by measuring the ratio of parent to daughter atoms and knowing the half-life, scientists calculate the time since the material formed. Carbon-14 (half-life $5{,}730$ years) dates organic remains up to about $50{,}000$ years, while potassium-40 and uranium-238 date igneous rocks that are millions to billions of years old. Decay follows first-order kinetics, $N = N_0 e^{-\lambda t}$, so the age is $t = \frac{1}{\lambda}\ln\left(1 + \frac{D}{N}\right)$, where $D$ is the daughter atoms produced and $\lambda$ is the decay constant. Reliable dating requires a closed system since formation and a known or negligible initial daughter content; isochron methods remove the initial-daughter assumption. Systems include $^{238}U \rightarrow ^{206}Pb$ (half-life $4.47$ billion years), $^{40}K \rightarrow ^{40}Ar$ ($1.25$ billion years), $^{87}Rb \rightarrow ^{87}Sr$ ($48.8$ billion years), and $^{14}C \rightarrow ^{14}N$ ($5{,}730$ years).

Example

Carbon dating told scientists that a mammoth bone was about $20{,}000$ years old by measuring how much of its radioactive carbon had decayed. Uranium-lead dating of zircon crystals in granite gives the age the magma cooled, and carbon-14 dating of charcoal from a Native American campsite along the Catawba River gives when the fire burned. Earth's age of $4.54$ billion years comes from lead isotope ratios in meteorites and the oldest terrestrial zircons. Argon-argon dating of sanidine in the ash at the Cretaceous-Paleogene boundary gives $66.0$ million years with a precision better than $0.1\%$.

Key Insight

Radioactive atoms are like a clock that started ticking when the rock formed, and scientists just read the clock. Radiometric dating usually dates igneous rock rather than the fossil itself; a fossil's age comes from dating the volcanic ash layers above and below it. Independent decay systems on the same rock give concordant ages, which is the strongest test of the method. Decay constants have been checked against each other and against astrophysical observations and have not changed measurably over Earth's history.